Product ID:N4760 1LT BLUE TREE MARKING PAINT
MSDS Date:10/31/1991
FSC:8010
NIIN:01-274-2573
MSDS Number: BMSSJ

NILES CHEMICAL PAINT

225 FORT ST.
NILES, MI 49120
US

Emergency Phone: 219-236-5856

Info Phone: 616-683-3377

Preparer: MIKE LICHATOWICH

Cage: 02388

NILES CHEMICAL PAINT

307 NILES, MI 49120 US

Telephone: 616-683-3377/219-236-5856

Cage: 02388

MINERAL SPIRITS (VP 2.0 MM @ 20 C)

CAS: 8052-41-3

Fraction By Weight: 48%

OSHA PEL 500 PPM

ACGIH TLV: 100 PPM; 9293

ALKYD RESIN

Fraction By Weight: 20%

COBALT COMPOUNDS (AS CO)(SARA 313)

CAS: 7440-48-4

Fraction By Weight: <1%

OSHA PEL 0.1 MG/M3;AS CO

ACGIH TLV: 0.05 MG/M3;DUST 9293

MANGANESE COMPOUNDS (AS MN)(SARA 313)

CAS: 7439-96-5

Fraction By Weight: <1%

OSHA PEL (C) 5 MG/M3 DUST

ACGIH TLV: 5 MG/M3 DUST 9293

PROPRIETARY INGREDIENTS

Fraction By Weight: BALANCE

4.35 LBS/GAL

RTECS: 9999999VO

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES- SEVERE IRRITATION, LACRIMATION,
REDNESS, BLURRED VISION, VISUAL DISTURBANCES & EYE BURNS. SKIN-
HARMFUL IF ABSORBED THROUGH SKIN. CAN BE ABSORBED IN TOXIC AMOUNTS,
ESPECIALLY FROM PROLONGED OR R EPEATED EXPOSURES. BREATHING- NASAL
& RESPIRATORY IRRITATION, CNS DEPRESSION (DIZZINESS, DROWSINESS,
WEAKNESS, FATIGUE,*
Effects of Overexposure:*CONFUSION) NAUSEA, HEADACHE, VERTIGO, POSSIBLE
UNCONSCIOUSNESS, EVEN ASPHYXIATION. SWALLOWING- GASTROINTESTINAL
IRRITATION, ABDOMINAL PAIN, NAUSEA, VOMITING, DIARRHEA, BLINDNESS &
EVEN DEATH. TARGET ORGANS- SKIN, EYES, RESPIRATORY SYSTEM,CNS, GI
TRACT.

First Aid:INHALE-MOVE TO FRESH AIR. IF BREATHING STOPPED, GIVE CPR. GET
MED AID ASAP. SKIN- WASH W/SOAP/WATER. EYE: IMMED FLUSH W/LG AMT
WATER-15 MIN, OCCASIONALLY LIFTING UPPER/LOWER LIDS. GET MED AID
IMMED. C ONTACT LENSES SHOULD NOT BE WORN WHEN WORKING W/THIS
MAT'L. SWALLOWING- INDUCE VOMIT IMMED BY GIVING 2 GLASSES WATER &
STICKING FINGER DOWN THROAT. NOTHING BY MOUTH UNCONSC PERSON. GET
MED AID IMMED.

Flash Point Method:TCC
Flash Point:102F,39C
Lower Limits:36.0
Upper Limits:0.8
Extinguishing Media:DRY CHEMICAL, FOAM, CO2.
Fire Fighting Procedures:WEAR SCBA W/FULL FACEPIECE OPERATED IN
POSITIVE PRESS MODE & FULL PROTECT CLOTH. USE WATER TO COOL CLOSED
CNTNR(PREVENT PRESS BUILD-UP & POSS AUTOIGNITE)W/HEAT.
Unusual Fire/Explosion Hazard:KEEP CNTNRS CLOSED TIGHT & FROM IGNITE
SOURCES. CLOSED CNTNRS MAY EXPLODE W/EXTREME HEAT, USE CAUTION.
OVEREXPOS TO DECOMP PROD MAY CAUSE HEALTH HZD.

Spill Release Procedures:REMOVE IGNITE SOURCES. MINIMIZE BREATHING OF
VAP & AVOID SKIN CNTCT. SMALL-ABSORB W/INERT MAT'L. SHOVEL
RECLAIMED LIQ & ABSORB TO RECOVERY/SALVAGE DRUMS FOR DISPOSAL.
LG-DIKE TO PREVENT FURTHER MOVEME NT & RECLAIM TO RECOVERY/SALVAGE
DRUMS/TANK TRUCK.

Handling and Storage Precautions:AVOID STORAGE IN HIGH TEMPERATURES
AREAS OR NEAR FIRE OR OPEN FLAME. KEEP CONTAINERS CLOSED WHEN NOT
IN USE. AVOID ROUGH HANDLING.
Other Precautions:CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN
EMPTY. DO NOT WELD OR FLAME CUT ON EMTPY DRUMS.

Respiratory Protection:WEAR APPROP (TYPE TC-23C-75) PROPERLY FITTED
HALF-MASK OR FULL FACEPIECE RSPRTR (NIOSH/MSHA) DURING & AFTER
APPLIC UNLESS AIR MONITORING DEMONSTRATES VAPOR/MIST LEVELS ARE
BELOW APPLICABLE LIMITS. FOL LOW RESPIRATOR MFR DIRECTIONS FOR USE.
Ventilation:PROVIDE SUFFIC VENT IN VOLUME/PATTERN TO KEEP AIR CONC
BELOW CURRENT APPLICABLE OSHA PERMISSIBLE EXPOSURE LIMIT OR **
Protective Gloves:CHEMICAL RESISTANT (NITRILE OR VITON)
Eye Protection:CHEM GOGGLES, SFTY GLASSES, FACE SHIELD
Work Hygienic Practices:WASH HANDS BEFORE EATING, SMOKING OR USING
RESTROOM.
Supplemental Safety and Health
WASH SKIN PROMPTLY IF CONTAM. REMOVE ANY CLOTHING THAT BECOMES WET (TO
AVOID FLAMM HZD). SYMPTOMS FROM USE MAY NOT BE IMMED APPARENT. GET
MEDICAL AID. **ACGIH'S TLV LIMIT. REMOVE DECOMP PRODUCTS FORME D
DURING WELDING OR FLAME CUTTING SURFACES COATED W/THIS PRODUCT. FOR
BAKING FINISHES-VENT VAPORS EMITTED ON HEATING.

HCC:F4
Boiling Pt:B.P. Text:146 TO 330F
Vapor Density:> AIR
Spec Gravity:8.90 LB/GL
Viscosity:40-45SZ#2
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:SLIGHT
Appearance and Odor:LIQUID, ODOR OF SOLVENTS.
Percent Volatiles by Volume:68.59

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:HIGH TEMPERATURES, SHOCK FROM DROPPING.
Hazardous Decomposition Products:CAN PRODUCE CARBON MONOXIDE AND/OR
CARBON DIOXIDE.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH APPLICABLE LOCAL,
STATE AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.